Supercritical fluid technology as a sustainable alternative method for textile dyeing: An approach on waste, energy, and CO2 emission reduction.

The clothing industry is considered one of the most polluting industries on the planet due to the high consumption of water, energy, chemicals/dyes, and high generation of solid waste and effluents. Faced with environmental concerns, the textile ennoblement sector is the most critical of the textile production chain, especially the traditional dyeing processes. As an alternative to current problems, dyeing with supercritical CO2 (scCO2) has been presented as a clean and efficient process for a sustainable textile future. Supercritical fluid dyeing (SFD) has shown a growing interest due to its significant impact on environmental preservation and social, economic, and financial gains. The main SFD benefits include economy and reuse of non-adsorbed dyes; reduction of process time and energy expenditure; capture of atmospheric CO2 (greenhouse gas); use and recycling of CO2 in SFD; generation of carbon credits; water-free process; effluent-free process; reduction of CO2 emission and auxiliary chemicals. Despite being still a non-scalable and evolving technology, SFD is the future of dyeing. This review presented a comprehensive overview of the environmental impacts caused by traditional processes and confronted the advantages of SFD. The SFD technique was introduced, along with its latest advances and future perspectives. Financial and environmental gains were also discussed.

Thermal, Morphological and Mechanical Properties of Multifunctional Composites Based on Biodegradable Polymers/Bentonite Clay: A Review.

The extensive use of non-biodegradable plastic products has resulted in significant environmental problems caused by their accumulation in landfills and their proliferation into water bodies. Biodegradable polymers offer a potential solution to mitigate these issues through the utilization of renewable resources which are abundantly available and biodegradable, making them environmentally friendly. However, biodegradable polymers face challenges such as relatively low mechanical strength and thermal resistance, relatively inferior gas barrier properties, low processability, and economic viability. To overcome these limitations, researchers are investigating the incorporation of nanofillers, specifically bentonite clay, into biodegradable polymeric matrices. Bentonite clay is an aluminum phyllosilicate with interesting properties such as a high cation exchange capacity, a large surface area, and environmental compatibility. However, achieving complete dispersion of nanoclays in polymeric matrices remains a challenge due to these materials' hydrophilic and hydrophobic nature. Several methods are employed to prepare polymer-clay nanocomposites, including solution casting, melt extrusion, spraying, inkjet printing, and electrospinning. Biodegradable polymeric nanocomposites are versatile and promising in various industrial applications such as electromagnetic shielding, energy storage, electronics, and flexible electronics. Additionally, combining bentonite clay with other fillers such as graphene can significantly reduce production costs compared to the exclusive use of carbon nanotubes or metallic fillers in the matrix. This work reviews the development of bentonite clay-based composites with biodegradable polymers for multifunctional applications. The composition, structure, preparation methods, and characterization techniques of these nanocomposites are discussed, along with the challenges and future directions in this field.

Fibrous microplastics released from textiles: Occurrence, fate, and remediation strategies.

Microplastics (MP), i.e., particles measuring less than 5 mm in size, are considered emerging pollutants. The ubiquity of MP is causing great concern among environmental and public health agencies. Anthropogenic activities are responsible for the extensive dispersal of MP in nature. Adverse effects on living organisms, interactions with other contaminants occurring in the environment, and the lack of effective degradation/removal techniques are significant issues related to MP. Most MP found in nature are fibrous (FMP). FMP originate from textile products, mainly synthetic fibers (e.g., polyester). Synthetic fibers are intensively used to produce countless goods due to beneficial characteristics such as high mechanical resistance and economic feasibility. FMP are ubiquitous on the planet and impart lasting adverse effects on biodiversity. Data on the consequences of long-term exposure to these pollutants are scarce in the literature. In addition, few studies address the main types of synthetic microfibers released from textiles, their occurrence, adverse effects on organisms, and remediation strategies. This review discusses the relevant topics about FMP and alerts the dangers to the planet. Furthermore, future perspectives and technological highlights for the FMP mitigation/degradation are presented.

Consequence analysis due to possible ethanol leaks in sugarcane biorefineries.

This study simulated and evaluated the consequences of possible ethanol leaks in a hypothetical sugarcane biorefinery, considering climatic factors in the region of the State of São Paulo-BR. The Gaussian model was used to obtain the results of the hypothetical scenarios. From these values, an empirical mathematical model was established to describe the behavior of the system within the investigated experimental domain. The results obtained the modeling values of the hypothetical scenarios, the statistical treatment for the two responses-a range, slight damage (R1), and a range, high damage (R2), the joint analyses of variables R1 and R2, and the risk classification of catastrophic events. The consequence analysis allowed the calculation and plotting of graphs, such as the areas of thermal radiation range. Among the variables addressed in the study, the diameter of the leakage hole was the most noticeable in the range of thermal radiation. Therefore, it is relevant to make simulations to prevent hazardous material leakages by applying the exact characteristics of the plant to conduct the procedure.